C–H functionalization of amines with aryl halides by nickel-photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details and characterization data. See DOI: 10.1039/c6sc02815b Click here for additional data file.

Photoredox mediated nickel catalyzed C(sp3)–H thiocarbonylation of ethers† †Electronic supplementary information (ESI) available: Experimental details and full characterization of substrates and products. Crystallographic data for compound [Ni-II]. CCDC 1516709. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02516e Click here for additional data file. Click here for additional data file.

The first direct C(sp)–H thiocarbonylation reaction is achieved by visible light photoredox/Ni dual catalysis. The thioester group of thiobenzoate is transferred to the a-oxy carbon of various cyclic/acyclic ethers, which is the opposite to the commonly expected chemical reactivity involving acyl group transfer via the weaker C(acyl)–S activation. Through mechanistic studies, we proposed that t...

Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details, spectral data, and crystallographic results. CCDC 1533276 and 1533274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01703k Click here for additional data file. Click here for additional data file.

Dual gold and photoredox catalysed C–H activation of arenes for aryl–aryl cross couplings† †Electronic supplementary information (ESI) available: Experimental procedures, full optimisation tables, control reaction, mechanistic studies, characterisation data and copies of NMR spectra of new compounds. See DOI: 10.1039/c6sc05469b Click here for additional data file.

A mild and fully catalytic aryl–aryl cross coupling via gold-catalysed C–H activation has been achieved by merging gold and photoredox catalysis. The procedure is free of stoichiometric oxidants and additives, which were previously required in gold-catalysed C–H activation reactions. Exploiting dual gold and photoredox catalysis confers regioselectivity via the crucial gold-catalysed C–H activa...

Tertiary amine mediated aerobic oxidation of sulfides into sulfoxides by visible-light photoredox catalysis on TiO2 † †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc01813g Click here for additional data file.

Photoredox ketone catalysis for the direct C–H imidation and acyloxylation of arenes† †Electronic supplementary information (ESI) available: Experimental procedures and characterization data for all relevant compounds. CCDC 1544882. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01700f Click here for additional data file. Click here for additional data file.

Acyloxylation of Arenes Chandra Bhushan Tripathi, Tsuyoshi Ohtani, Michael T. Corbett and Takashi Ooi*‡ Institute of Transformative Bio-Molecules (WPI-ITbM), ‡ Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8601, Japan ‡CREST, Japan Science and Technology Agency (JST), Nagoya University, Nagoya 464-8601, Japan [email protected]...